To evolve Toxel into Toxtricity, you'll need to level it up while its nature is either Plus or Minus. If Toxel's nature is Plus, it will evolve into Amped Form Toxtricity. If its nature is Minus, it will evolve into Low Key Form Toxtricity.
To check a Pokémon's nature, look at its summary screen in the party menu. It will list one of 25 possible natures, including Plus and Minus. You can also use an Ability Capsule held item to change a Pokémon's nature.
Make sure Toxel gains experience in battles until it reaches level 30. At that point, it will glow brightly and evolve into either Amped or Low Key Toxtricity, depending on its original nature. The new Toxtricity will know new moves and its appearance and type will change as well.
Related tutorial videos:
How to get Toxel and Evolve into Toxtricity - Pokemon Sword and Shield
How To Evolve Toxel Into Toxtricity In Pokemon Scarlet And Violet | Paldea Pokedex
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